Covalent POM–Ir hybrid assemblies: tuning redox properties for light-driven multiple charge accumulation

Chem. Commun., 2025, Advance Article DOI: 10.1039/D5CC01951F, Communication Nicolas Queyriaux, Maria Wächtler, Christian Cariño, Sandra Alves, Benjamin Dietzek-Ivanšić, Vincent Artero, Anna Proust, Murielle Chavarot-Kerlidou, Guillaume Izzet Fine tuning of the polyoxometalate electron reservoir properties unlock light-driven accumulation of three electrons on a polyoxomolybdate-based photoactive assembly.