Thionyl fluoride as a sulfur(IV) SuFEx hub for the efficient syntheses of sulfinamides and sulfinate esters

Chem. Commun., 2024, 60,9765-9768 DOI: 10.1039/D4CC02876G, Communication William P. Chappell, Marie Favié, Glenn M. Sammis Herein, we demonstrate a method for the syntheses of sulfinamides and sulfinate esters using a novel sulfur(IV) fluoride exchange reaction with organometallic reagents.