Recent advances in catalytic asymmetric metalloid–hydrogen bond insertion of transition-metal carbenes

Chem. Soc. Rev., 2025, Advance Article DOI: 10.1039/D5CS00195A, Review Article Shuyue Zhang, Ming-Hua Xu This review provides an overview of recent progress and advances in transition-metal-catalyzed asymmetric carbene insertion into metalloid–hydrogen bonds (B–H/Si–H/Ge–H), emphasizing ligand design, mechanistic studies, and synthetic applications.