Modular assembly of amines and diborons with photocatalysis enabled halogen atom transfer of organohalides for C(sp3)–C(sp3) bond formation

Chem. Sci., 2025, Advance Article DOI: 10.1039/D5SC00190K, Edge Article Rong-Bin Liang, Ting-Ting Miao, Xiang-Rui Li, Jia-Bo Huang, Shao-Fei Ni, Sanliang Li, Qing-Xiao Tong, Jian-Ji Zhong A new photocatalytic approach by using the assembly of DABCO A1 and B2Nep2 B1 has been established to enable the cross-coupling of organohalides and alkenes for C(sp3)–C(sp3) bond formation.