Low-Coordinate Calcium Peroxide and Oxide Complexes

Chem. Commun., 2025, Accepted Manuscript DOI: 10.1039/D5CC03340C, Communication Stefan Thum, Marcel A. Schmidt, Jens Langer, Sjoerd Harder A Ca(I) synthon with superbulky beta-diketiminate ligands (BDI*) and a N2(2–) dianion, [(BDI*)Ca]2(N2), is key to the synthesis of binuclear (BDI*)Ca(mu2-O2)Ca(BDI*) and (BDI*)Ca(mu2-O)Ca(BDI*) complexes. The Ca oxide complex is particularly...