Expression of hyperconjugative stereoelectronic interactions in borazines

Chem. Commun., 2024, Accepted Manuscript DOI: 10.1039/D4CC05188B, Communication Vivek Chandrakant Wakchaure, Jacopo Dosso, Davide Bonifazi, Martina Crosta, Hanspeter Kählig, Benjamin D. Ward This paper discusses hyperconjugative stereoelectronic effects in borazines. A series of alkyl-substituted borazines were synthesized and analysed by NMR spectroscopy and X-ray diffraction. Supported by NBO analyses, the significant decreases...