Non-spectator Behavior of a Neutral Phosphine Ligand Driven by a Redox-Active Boron Cluster

Chem. Sci., 2025, Accepted Manuscript DOI: 10.1039/D5SC04058B, Edge Article Jared R. Riffle, Cash L Jowers, Sarah Luna, Mark D. Smith, Dmitry V. Peryshkov A new concept of ligand ambiphilicity that relies on the redox behavior of the indirectly coordinated boron cluster scaffold instead of the direct involvement of a single center in a...