Physical Review Letters
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Observation of Spin-Singlet Butterfly Rydberg Molecules in an Ultracold Atomic Rb Gas
Author(s): Markus Exner, Rohan Srikumar, Richard Blättner, Peter Schmelcher, H. R. Sadeghpour, Matthew T. Eiles, and Herwig Ott
We report the observation of spin-singlet ultralong-range Rydberg butterfly molecules consisting of a ground-state atom bound to a Rydberg atom by $P$-wave scattering of $^{87}\mathrm{Rb}$ Rydberg electrons from $^{87}\mathrm{Rb}(5\text{ }\text{ }\mathrm{s})$ atoms. A three-photon excitation scheme … [Phys. Rev. Lett. 136, 243002] Published Thu Jun 18, 2026