Photoredox radical Truce−Smiles rearrangement of N-sulfinyl acrylamides with sulfoxonium ylides

Chem. Commun., 2025, Accepted Manuscript DOI: 10.1039/D5CC03513A, Communication Lin Tian, Pu Chen, Lindong Xiao, Huawen Huang The visible light-induced Truce-Smiles rearrangement reaction of N-sulfinyl acrylamides with sulfoxonium ylides is herein reported. The reaction was performed under mild conditions by radical addition/aryl migration, allowing the synthesis of...