Rh-Catalyzed Enantioselective Hydrosilylation of Unactivated Alkenes

Chem. Sci., 2025, Accepted Manuscript DOI: 10.1039/D5SC02711J, Edge Article Yichen Wu, Hao-Yang Qian, Heng Zhang, Jian-Ye Zou, Qing-Yan Wu, Xiao-Xue Nie, Long Zheng, Qian Peng, Peng Wang Here, we report a highly efficient rhodium-catalyzed enantioselective hydrosilylation of unactivated alkenes, achieving excellent regioselectivity and high enantioselectivity. The use of a commercially available chiral ferrocene-based phosphine-oxazoline ligand was crucial...