Thermal- and Light-Induced Valence Tautomerism with a Concerted Spin Transition in an Iron Tris(diimine) Complex

Chem. Sci., 2025, Accepted Manuscript DOI: 10.1039/D4SC07798A, Edge Article Jett Tao Janetzki, Dominic Stuart Brown, Florian Daumann, Ismath Haseena Ismail, Robert William Gable, Moya Hay, Roger J Mulder, Alyona A. Starikova, Birgit Weber, Marcus J. Giansiracusa, Colette Boskovic The switching phenomena of spin crossover (SCO) and valence tautomerism (VT) are respectively dominated by iron(II) and cobalt-dioxolene systems. To explore new possibilities for SCO or VT, the redox-active α-diimine...