A tetranuclear lanthanum-nickel hydrido complex supported by arene-anchored bis(phosphinomethylamido) ligand

Chem. Commun., 2026, Accepted Manuscript DOI: 10.1039/D5CC06726J, Communication Xiuyan He, Changjiang Wu, Dongjing Hong, Huayi Fang, Peng Cui Tetranuclear La(III)-Ni(0) iodide and hydride complexes featuring a Ni(0)→La(III) dative bond were synthesized and characterized by NMR spectroscopy, X-ray diffraction and computational analysis. The hydrido complex showed insertion reactivity with...