Alkaline-adaptive covalent organic framework photocatalysts: synergistic molecular orbital and hydrogen-bond network engineering for H2O2 production

Chem. Sci., 2026, Accepted Manuscript DOI: 10.1039/D5SC08298F, Edge Article Zhiwu Yu, Jiayi Zhang, Xiaolong Zhang, Xuwen Sun, Guihong Wu, Zhiyun Zhang, Fengtao Yu, Jianli Hua Alkaline hydrogen peroxide (H2O2) is highly desirable for critical applications due to its superior stability and reactivity, but is incompatible with conventional near-neutral production methods. While covalent organic frameworks (COFs)...