Chem. Sci., 2026, Accepted Manuscript DOI: 10.1039/D6SC02907H, Edge Article Charlotte E. R. van Halteren, Christoph Wölper, Leon Kapp, Stephan Schulz The controlled assembly of molecular pnictogen–tellurium (Pn–Te) frameworks remains a longstanding synthetic challenge due to the intrinsic lability of Pn–Te bonds, particularly of the heaviest pnictogens, resulting in a scarcity...