Chem. Sci., 2025, Accepted Manuscript DOI: 10.1039/D5SC05591A, Edge Article lingran Liu, Meilin Yu, Wei Tuo, Yue Zhao, Fengmin Zhang, Yan Sun Positional isomerism plays a pivotal role in governing the assembly pathways of hierarchical architectures by modulating both the thermodynamic landscape and kinetic trajectories through precise spatial control of the constituent...