Chem. Commun., 2025, Accepted Manuscript DOI: 10.1039/D5CC04914H, Communication Ke Jiang, Ling Chen, Yuhui Liang, Bo Duan Symmetry breaking is difficult to achieve in achiral systems as nonselective supramolecular self-assembly typically results in racemic mixtures. Here, we reported a novel finding of spontaneous supramolecular chiral formation in...