Constructing Mo–O–Ni anchoring bonds by room temperature solid-state reduction to drive hydrogen spillover for saturated hydrogenation of naphthalene
Chem. Commun., 2026, Advance Article DOI: 10.1039/D6CC02391F, Communication
Guo Chen, Jinhua Wang, Tingting Cui, Yakun Tang, Yue Zhang, Ting Liu, Xiaodong Zhou, Xiaodong Guo, Lang Liu Mo–O–Ni anchoring bonds for hydrogen spillover constructed via room temperature solid-state reduction. 12%-PMA@Ni enables efficient deep hydrogenation of naphthalene to decalin. DFT reveals H2 barrier 0.31 eV and naphthalene adsorption −1.75 eV.
