Chem. Commun., 2025, Accepted Manuscript DOI: 10.1039/D5CC04051E, Communication Cham Wah Cheung, Edmund C. M. Tse Alcohol phosphorylation is key to produce phosphate monoester, which is traditionally generated under harsh conditions using hazardous reagents. Here, we develop one-step electrochemical phosphorylation to synthesize phosphate monoester under ambient...