From Spontaneous Ligand Evolut... Note

From Spontaneous Ligand Evolution to High-Throughput Water-Based Synthesis: Scalable Access to CO2 Selective Mixed-Ligand Metal Organic Frameworks

Chem. Commun., 2025, Accepted Manuscript DOI: 10.1039/D5CC03218K, Communication Thomas Howlett, Ziqi Wang, Wendy Tang, Nyati Arora, Prapti M. Shende, Phillip Liu, Sneha Kumari, Monu Joy, Mario Wriedt, Ronald A. Smaldone, Jeremiah J Gassensmith We report the discovery and synthesis of MOXI-214, a manganese-based metal-organic framework (MOF) with high selectivity for CO₂ adsorption. Oxalate ligands were generated by in situ ligand evolution from sodium...