Chem. Commun., 2025, Accepted Manuscript DOI: 10.1039/D5CC03279B, Communication Zanjila Azeem, Sunny Maurya, Abhishek Kumar Gupta, Shalini ., Ruchir Kant, Pintu Kumar Mandal We disclose a copper-catalyzed C2- or C3-thioglycosylation of indole with a shelf-stable and odorless glycosyl thiosulfonate to assemble indole alkaloid glucoside frameworks. This straightforward, catalytic system exhibits features of broad...