Chem. Commun., 2026, Accepted Manuscript DOI: 10.1039/D6CC03098J, Communication Yi-Feng Jiang, Jia-Wen Liu, Jun-Jie Ma, Shenghu Yan, Hong-Kai Sha, Jia-Yin Wang A photoredox-catalyzed 1,2-carboimination of unactivated alkenes via radical N-N bond cleavage and remote 1,4-amino migration is described. Employing fac-Ir(ppy)3 as catalyst and 1,4-dioxane as solvent and HAT reagent, the reaction...