Iridium-Catalyzed P(III)-Directed ortho-C-H Silylation of Arylphosphines with Hydrosilanes

Chem. Commun., 2026, Accepted Manuscript DOI: 10.1039/D5CC06762F, Communication Weiwei Cheng, Liang Zhang, Weiming Hong, Yikai Tao, Zheng Zhang An iridium-catalyzed, P(III)-directed modular ortho-C–H silylation of commercial monophosphine ligands with readily available trialkylsilanes of varying steric and electronic properties was achieved. This ligand-free strategy exhibits mild condition, broad substrate...