Chem. Sci., 2025, Accepted Manuscript DOI: 10.1039/D5SC05740J, Edge Article Renming Pan, Jie Zhu, Xinjie Zhou, Minyan Wang, Ping Lu The palladium-catalyzed enantioselective redox-neutral coupling of alkenes with organoboronic reagents remains an unfulfilled challenge. Herein, we report a divergent palladium-catalyzed enantioselective hydroarylation of cyclobutenes with arylboronic acids, affording both 1,2-...