Chem. Sci., 2025, Accepted Manuscript DOI: 10.1039/D5SC05365J, Edge Article Borja Ortín-Rubio, Yunhui Yang, Emilio Borrego-Marin, Jaume Rostoll-Berenguer, Carlos Vila, Judith Juanhuix, Inhar Imaz, Jorge A R Navarro, Daniel Maspoch Metal–organic frameworks (MOFs) based on highly connected nets continue to expand the landscape of reticular chemistry, with zirconium (Zr) and rare-earth (RE) clusters offering ideal nodes for the construction of...