Chem. Sci., 2026, Accepted Manuscript DOI: 10.1039/D6SC02045C, Edge Article Minjung Kang, Zhenhuan Sun, Klaus Schmidt-Rohr, Seth M Cohen Polymer-grafted metal-organic frameworks (MOFs) address the powder form and poor processability of crystalline MOFs by forming free-standing self-assembled MOF monolayers (SAMMs). However, to date, SAMMs have been limited to microporous...