Chem. Commun., 2025, Accepted Manuscript DOI: 10.1039/D5CC04781A, Communication Chun-Yan Liu, Yunjing Mu, Wu-Ji Chen, Cheng-Shuai Liu, Chang-Gen Lin, Yu-Fei Song We report here the supramolecular assembly between a new asymmetric polyoxometalate hybrid and α-/γ-CDs, which leads to novel pseudo-rotaxane and poly-pseudo-rotaxane structures that have been thoroughly characterized in solution and...