Chem. Sci., 2026, Accepted Manuscript DOI: 10.1039/D6SC03994D, Edge Article Aslam C Shaikh, Kavneet Kaur, PUJA SINGH, Rahul D Thombare, Adithya K. P., Manoj V. Mane Dearomative cycloaddition reactions of indoles offer a powerful strategy for rapidly increasing molecular complexity, yet intermolecular variants that proceed with high regio-and diastereocontrol remain uncommon. Herein, we report an iron(III)...