Chem. Sci., 2025, Accepted Manuscript DOI: 10.1039/D5SC05510E, Edge Article Jinbo Hu, Xinyan Liu, Yeqi Du, Wenbo Wang, Tianchang Wang, Hao Zhang, Ranlong Duan, Xinchao Bian, Xuesi Chen The development of high-performance, renewable polyesters with tunable mechanical properties is critical for advancing sustainable materials to replace petroleum-based plastics. Herein, a conceptually simple but highly effective strategy was employed...