Synthesis, Characterization, and Imidogen Photochemistry of a Hydrazoic Acid Adduct of Rh2

Chem. Sci., 2026, Accepted Manuscript DOI: 10.1039/D6SC02258H, Edge Article Arpan Paikar, Phong Thai, Matthew T Figgins, Bodhisattwa Mandal, Matthew Lekas, Joseph Reibenspies, Gerard Van Trieste, David Charles Powers Metal-imidogen (i.e., M-NH) intermediates are proposed in metal-catalyzed NH-transfer reactions. Transition metal complexes of hydrazoic acid (HN3) could serve as precursors to these transient intermediates; however, the coordination chemistry of...