Chem. Sci., 2025, Accepted Manuscript DOI: 10.1039/D5SC05704C, Edge Article Prantik Mondal, Debobroto Sensharma, Seth M Cohen Polymer-metal-organic frameworks (polyMOFs) represent an unusual class of polymer-MOF hybrids, but inadequate methods for designing and tailoring their underlying polymeric building blocks has been a limitation of these systems. Previous...