Chem. Sci., 2025, Accepted Manuscript DOI: 10.1039/D5SC06269A, Edge Article Rowan L Pilkington, Rosa Kössler, Jesse Molloy, Stefan Bräse, Daniel L Priebbenow Siloxycarbene intermediates induced via the visible light irradiation of acylsilanes undergo highly efficient benzoin-type click reactions with pyruvate derivatives. This process requires no reagents other than visible light, proceeds with...