RSC | Chem. Sci. latest articles 中文 关注 钯催化芳基亲电试剂的叠氮化反应机理：碳酸盐促进的转金属化与配体依赖的选择性 Chem. Sci., 2026, 接受手稿 DOI: 10.1039/D6SC04320H, Edge Article Torben Rogge, Wolfgang Obermayer, Martin Oestreich 报道了对硅基化二氮烯作为二氮烯基阴离子等价物与芳基亲电试剂进行钯催化交叉偶联的量子化学研究。选择性，即通过二氮烯化生成偶氮苯与生成联芳基…… Mechanism of the Palladium-Catalyzed Diazenylation of Aryl Electrophiles: Carbonate-Facilitated Transmetalation and Ligand-Dependent Selectivity pubs.rsc.org
